A five-hour pause in the Syrian government's assault on the rebel-held Eastern Ghouta outside Damascus is under way, although both sides have reported fresh artillery attacks.
The government's ally Russia ordered the pause to allow civilians to leave.
It is not clear if agencies will also be able to deliver aid to the area, where 390,000 people have come under relentless bombardment in recent days.
The US has urged Russia to use its influence to secure a 30-day truce.
The UN Security Council unanimously passed a resolution demanding a nationwide cessation of hostilities on Saturday, but it was not given a specific start date.
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